Malcolm L. Legault
Colorado State University Cooperative Extension
All pesticides are toxic; toxicity x exposure = risk. Some pesticide labels require the use of Personal Protective Equipment (PPE). This requirement protects the handler from poisonings when mixing, loading and applying pesticides. Pesticides improperly handled increases the level of risk because the exposure level increases. Reading and following the directions on the pesticide label will help protect the user and derive the most benefit from the selected pesticide.
Chemical-resistant PPE is material that pesticides cannot penetrate during the time required to complete the pesticide handling task. Use appropriate PPE when mixing and applying pesticides and when cleaning equipment used to apply pesticides. Never enter an area where pesticides are being used without PPE.
Materials used in PPE are resistant to a particular pesticide but may not provide a constant level of protection over time. Some materials protect for extended periods and others protect for just a few minutes. Exposure time is the term used to define chemical resistance. For example, neoprene may be resistant to one solvent, used in the formulation of a pesticide, for 30 minutes or less and to another solvent for more than four hours. Disposable plastic gloves, shoe covers and other PPE may provide only enough protection for tasks that can be completed in a few minutes.
Pesticides enter PPE material on contact and continue to move into and through the material until the source is removed. Therefore, rinsing the PPE with clean water after each use will extend the protective life. When putting on or removing PPE, use caution, the outer surface may be contaminated with pesticides. When removing any PPE, do not allow it to touch skin or lightly covered areas. Do not take a deep breath, contamination can result from inhalation of pesticides.
PPE constructed of sturdy materials are recommended for tasks that involve walking through rough terrain or handling sharp objects. Punctures or other damage to the PPE material reduces the protective qualities.
No single material can protect against all pesticide products. Chemical resistance depends on whether the pesticide is liquid or dry and what diluents, solvents and concentrations are used in the agricultural chemical. The label may state what materials are resistant to the pesticide. If the label does not state the PPE material required for protection, contact the Toxic Substances Branch of the EPA, Colorado State University Cooperative Extension, the manufacturer of the pesticide or the PPE dealer in your area. To check whether a plastic or rubber is resistant to a pesticide, use a sample of the material and expose it to the pesticide for the longest period of time that you would wear the PPE. If the material does any of the following, discard the PPE and choose another:
- changes color,
- becomes soft or spongy,
- swells or bubbles,
- dissolves or becomes jelly-like, or
- becomes stiff or brittle.
for personal protective equipment:
Wear long-sleeved shirts and long pants. Fasten the collar to protect the lower neck. Wear coveralls over the shirt and pants. The coveralls should fit loosely, which creates an air barrier that reduces direct contact with the pesticide. When wearing two-piece coveralls, leave the top outside and extend below the waist. Coveralls should protect everything except the feet, hands, neck and head. If the pesticide is highly or moderately toxic, the coveralls should be chemical-resistant. If the coveralls are not chemical-resistant, wear a chemical-resistant apron.
Chemical-resistant coveralls can be very hot to wear and can lead to heat stress. Use the following precautions to reduce heat stress:
- select the coolest PPE appropriate for the task;
- schedule work at the coolest time of the day;
- increase the amount of water intake to compensate for water lost to perspiration;
- if the air temperature is high, rest frequently to allow the body to cool;
- if at any time perspiration is no longer produced, stop working immediately.
When wearing a chemical-resistant apron, choose one that reaches from the neck to the knees. If working around machinery, do not wear an apron, it can easily become caught in the machinery; wear chemical resistant coveralls instead.
Handle clothes worn during pesticide application as if they were contaminated. Handle all contaminated clothing with gloves. Wash the clothing daily and separate from the family wash. Prerinse or presoak the contaminated clothing using hot water. Use heavy-duty liquid detergent washing only a few items at a time with the highest water level and the longest wash time. Line dry the clothing. After washing, run the washer through a complete cycle with detergent.
Hand and Foot Protection
Hands and forearms receive the most pesticidal exposure. Eighty-five percent of dermal exposure occurs on the hands and forearms. This exposure can be reduced to 3 percent with the use of unlined, chemical-resistant gloves. Use of unlined gloves prevents absorption of pesticides to the inside surface of the glove. Wear chemical-resistant gloves when using any kind of pesticide. Refer to pesticide labels for stated requirements of certain types of glove material. Wear gloves that reach at least halfway to the elbow. This will keep pesticides from running down the sleeves and into the gloves. Put sleeves over the gloves and fasten the cuff, unless working over head. If applying pesticides over head, fold the glove to make a cuff.
Leave the gloves on when adjusting equipment or opening pesticide containers. Do not wipe your face when gloves are worn. Leave the gloves on until the entire task is complete. Removing the gloves increases the likelihood of contamination. After completing the task, wash your hands with the gloves on, remove the gloves and thoroughly wash and dry your hands.
To decrease exposure levels in the leg area, wear pant legs outside the boots or fasten shoe covers tightly to the pant leg. This keeps pesticides from running down the pant leg and collecting in boots or shoes.
Canvas, cloth and leather are difficult or impossible to clean adequately, and should not be worn as foot protection. Spills are often made when handling pesticides. Such spills are likely to land on or near the feet. Wear chemical-resistant footwear for spill protection, which can be shoes, shoe covers or boots. Remember to clean the footwear before removal to reduce the contamination from pesticides.
Gloves or footwear made of polyvinyl chloride (PVC) or rubber (butyl, nitrile, neoprene or natural rubber) must be at least 14 mils.(1) thick. If gloves or footwear are exposed previously to agricultural chemicals and irritation of the skin occurs when they are put on, wash the affected area immediately for at least 15 minutes and dry. Replace the footwear or gloves with clean pairs. Keep several pairs of gloves and footwear available to change whenever necessary.
Head and Neck Protection
To protect the head and neck from exposure to pesticides, wear a chemical-resistant, wide-brimmed hat or hood. Plastic "safari" hats, with a plastic sweatband, are a good choice and are relatively cool. Some chemical-resistant jackets or coveralls have an attached protective hood. If the hood is not used, tuck the hood inside the neckline to keep it from collecting pesticides.
Protective Eye Wear
Eyes are very sensitive to pesticides. Wear protective eye wear when handling pesticides. The different types of protective eye wear are shielded safety glasses, face shields and goggles. Shielded safety glasses must have brow and side shields. They do not cause fogging or sweating and give eye protection in many situations. Face shields provide protection to the entire face. Face shields that are cupped inward toward the throat give better protection than straight face shields.
Wear goggles when riding in an open cab during an air blast application, flagging under an aerial application, applying mists, fogs or aerosols indoors or working in similar situations. Goggles provide better protection than shielded safety glasses or face shields for these situations. Goggles should fit tightly against the face. A full-face respirator also protects the applicator in these situations. If worn with a half mask respirator select styles that fit comfortably with the respirator.
For additional information, contact your Colorado State University Cooperative Extension county agent or Cooperative Extension safety specialist, (303) 491-6172.
Cooperative Extension, Colorado State University. Published August 1993. Copyright 1993. For more information, contact your county Cooperative Extension office.
Colorado State University Cooperative Extension agricultural safety coordinator and research associate; agricultural and chemical engineering.
Publication #: 5.021
Disclaimer and Reproduction Information: Information in NASD does not represent NIOSH policy. Information included in NASD appears by permission of the author and/or copyright holder. More
Reviewed for NASD: 04/2002